Ions in solution

Ions in solution: basic principles of chemical interactions

by Burgess, John

Type Book
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This outline of the principles and chemical interactions in inorganic solution chemistry delivers a course module in an area of considerable complexity. Problems with solutions and tutorial hints to test comprehension have been added as a feature to check readers' understanding and assist self-study. Exercises and projects are also provided to help readers deepen and extend their knowledge and understanding. Inorganic solution chemistry is treated thoroughlyEmphasis is placed upon NMR, UV-VIS, …

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Title Statements

  • Full title :Ions in solution : basic principles of chemical interactions / John Burgess.

Summary

This outline of the principles and chemical interactions in inorganic solution chemistry delivers a course module in an area of considerable complexity. Problems with solutions and tutorial hints to test comprehension have been added as a feature to check readers' understanding and assist self-study. Exercises and projects are also provided to help readers deepen and extend their knowledge and understanding. Inorganic solution chemistry is treated thoroughlyEmphasis is placed upon NMR, UV-VIS, IR Raman spectroscopy, X-ray diffraction, and such topics as acid-base behaviour, stability constants and kinetics.

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Edition Statements

  • Publication Date:©1999
  • Edition:Second edition

Publication Statements

  • Publisher(s):Woodhead Publishing
  • Place of Publication:Cambridge, England
  • Language:eng
  • Publication Date:©1999

The Physical Object

  • Description:1 online resource (232 pages) : : illustrations

Edition Identifiers

  • ISBN:9781782420569, 1782420568
  • oclc:ocn874158519
  • LC Classification:QD561
  • Dewey Decimal:781.63

Table of Contents

Front Cover; Ions in Solution: Basic Principles of Chemical Interactions; Copyright Page; Table of Contents; Author's preface; List ofsymbols and abbreviations; Chapter 1. Introduction; 1.1 Dissolution of salts; 1.2 Metal ions around the Periodic Table; 1.3 New aqua-metal ions; 1.4 Anions and complexes in solution; 1.5 Model for ions in solution; Chapter 2. Solvation numbers; 2.1 NMR spectroscopy; 2.2 Ion movement methods; 2.3 Review of solvation numbers; Chapter 3. Ion-solvent distances; 3.1 X-ray diffraction by solutions; 3.2 Radial distribution functions.

3.3 Results of diffraction and scattering studiesChapter 4. Ion-solvent interactions; 4.1 Ultraviolet-visible spectroscopy; 4.2 Infrared and Raman spectroscopy; 4.3 Thermochemistry of ion solvation; Chapter 5. Acid-base behaviour; hydrolysis and polymerisation; 5.1 pK values for aqua-metal ions; 5.2 Polymerisation; 5.3 Anions and ligands; 5.4 Complexes; Chapter 6. Stability constants; 6.1 Definitions; 6.2 Trends; 6.3 Chelates; 6.4 Selectivity; macrocyclic and encapsulating ligands; 6.5 Relevance; Chapter 7. Redox potentials; 7.1 Introduction and thermodynamics; 7.2 Aqua-metal ions.

7.3 Complexes7.4 Redox potentials and stabi…

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