Title Statements
- Full title :Organic chemistry as a second language : second semester topics / David Klein.
Edition Statements
- Publication Date:©2020
- Edition:5e [Fifth edition]
Publication Statements
- Publisher(s):Wiley
- Place of Publication:Hoboken, NJ
- Language:eng
- Publication Date:©2020
Notes
Includes index.
The Physical Object
- Description:v, 292, 94, 8 pages : : illustrations ; : 26 cm
Edition Identifiers
- ISBN:9781119493914, 1119493919
- oclc:on1131718685
- LC Classification:QD256 $b .K541452 2020
- Dewey Decimal:547.0071/1
Table of Contents
1. Aromaticity -- Introduction to aromatic compounds -- Nomenclature of aromatic compounds -- Criteria for aromaticity -- Lone pairs -- 2. IR spectroscopy -- Vibrational excitation -- IR spectra -- Wavenumber -- Signal intensity -- Signal shape -- Analyzing an IR spectrum -- 3. NMR spectroscopy -- Chemical equivalence -- Chemical shift (benchmark values) -- Integration -- Multiplicity -- Pattern recognition -- Complex splitting -- No splitting -- Hydrogen deficiency index (degrees of unsaturation) -- Analyzing a proton NMR spectrum -- CNMR spectroscopy -- 4. Electrophilic aromatic substitution -- Halogenation and the role of Lewis acids -- Nitration -- Friedel-crafts alkylation and acylation -- Sulfonation -- Activation and deactivation -- Directing effects -- Identifying activators and de-activators -- Predicting and exploiting steric effects -- Synthesis strategies -- 5. Nucleophilic aromatic substitution -- Criteria for nucleophilic aromatic substitution -- Snar mechanism -- Elimination-addition -- Mechanism strategies -- 6. Ketones and aldehydes -- Preparation of ketones and aldehydes -- Stability and reactivity of c=o bonds -- H-nucleophiles -- O-nucleophiles -- S-nucleophile…
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