Polyoxometalate chemistry

by Eldik, Rudi van

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Title Statements

Full title :Polyoxometalate chemistry / ed. by Rudi van Eldik, Leroy Cronin.

Edition Statements

Publication Date:2017

Publication Statements

Publisher(s):Academic Press
Place of Publication:Cambridge, MA
Language:eng
Publication Date:2017

Notes

Includes index.

The Physical Object

Description:346 p. : : ill.

Edition Identifiers

ISBN:9780128111055, 0128111054
oclc:on1041387455

1. Mechanisms for the Aerobic Oxidation of Organic Compounds2. The H5PV2Mo10O40 Polyoxometalate and Electron Transfer Oxidations ; 3. The First Example of Electron Transfer-Oxygen Transfer Catalyzed by H5PV2Mo10O40 ; 4. Oxidation of Sulfides ; 5. Oxidation of Primary and Vicinal Alcohols ; 6. Oxidation of via Activation of C-H Bonds Revisited ; 7. Insertion of Oxygen Into a Carbon-Metal Bond ; 8. The Structure of H5PV2Mo10O40 During the Catalytic Reaction ; 9. Conclusions ; Acknowledgments ; References ; Chapter Four: Oxygen-Isotope Exchange and Metastable Dissociation in Oxides ; 1. Introduction

2. Broad Reactivity Trends for Dissolving Materials and Glasses3. Acid-Base Chemistry and Reactivity in Niobates ; 4. The Transition to a Partly Detached Structure in MAl12 Cations ; 5. Metastable Intermediates ; 6. Conclusions ; Acknowledgments ; References ; Chapter Five: Polyoxometalate Multielectron Catalysts in Solar Fuel Production ; 1. Introduction ; 2. Definitions ; 2.1. Reaction Thermodynamics of Water Splitting ; 2.2. Photochemical Generation of Oxidant/Reductant ; 3. Water Splitting Overview ; 3.1. Experimental Approaches to Evaluate WOCs and Water Reduction Catalysts

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