Stereochemistry: a three-dimensional insight

by Karnik, Anil V.

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Title Statements

Full title :Stereochemistry : a three-dimensional insight / Anil V. Karnik, Mohammed Hasan.

Edition Statements

Publication Date:2021.

Publication Statements

Publisher(s):Elsevier
Place of Publication:Amsterdam
Language:eng
Publication Date:2021.

Notes

Includes index.

The Physical Object

Description:1 online resource

Edition Identifiers

ISBN:9780128210635, 012821063X
oclc:on1261380194
LC Classification:QD481
Dewey Decimal:541.223

Front Cover -- Stereochemistry -- Copyright Page -- Contents -- About the authors -- Foreword -- Preface -- I. Fundamentals of stereochemistry -- 1 Basic concepts of structure and stereochemistry -- 1.1 Introduction -- 1.2 A brief history -- 1.3 Molecular geometry -- 1.3.1 Van der Waals' radius -- 1.3.2 Bond length -- 1.3.3 Bond angle -- 1.3.4 Dihedral angle -- 1.4 Isomers -- 1.4.1 Conformational isomers -- 1.4.2 Configuration and configurational isomers -- 1.5 Projection formulae -- 1.5.1 Fischer projection -- 1.5.2 Newman projection -- 1.5.3 Sawhorse projection

Questions and Problems -- References -- 3 Elements of chirality and chiral stereoisomerism -- 3.1 Introduction -- 3.2 Molecules with central chirality -- 3.2.1 Configurational descriptors for molecules with central chirality -- 3.2.1.1 The D-L system -- 3.2.1.2 The R/S system -- 3.3 Molecules with two or more chiral centres -- 3.3.1 Constitutionally unsymmetrical chiral molecules -- 3.3.1.1 Erythro and Threo -- 3.3.1.2 Pref and Parf -- 3.3.1.3 Like (l) and unlike (u) -- 3.3.1.4 Anti and Syn notations -- 3.3.1.5 Brewster's system

3.3.2 Stereoisomerism in constitutionally symmetrical chiral molecules -- 3.3.3 Stereoisomer…