The Power of Click Chemistry for Molecular Machines and Surface Patterning
The union of covalent and noncovalent chemistries manifested in the mechanical bond represents one of the great chemical triumphs of the last half century. However, until recently, the preparation of mechanically interlocked compounds has often been an inefficient and limiting process. This thesis provides a detailed account of the great strides taken to increase the synthetic accessibility of donor-acceptor mechanically interlocked molecules by the application of highly efficient and ultra mil…
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- Full title :The Power of Click Chemistry for Molecular Machines and Surface Patterning.
Summary
The union of covalent and noncovalent chemistries manifested in the mechanical bond represents one of the great chemical triumphs of the last half century. However, until recently, the preparation of mechanically interlocked compounds has often been an inefficient and limiting process. This thesis provides a detailed account of the great strides taken to increase the synthetic accessibility of donor-acceptor mechanically interlocked molecules by the application of highly efficient and ultra mild chemical transformations during their template-directed synthesis. These new departures in synthesi.
Read More ↓Edition Statements
- Publication Date:2011.
Publication Statements
- Publisher(s):Springer
- Place of Publication:Dordrecht
- Language:eng
- Publication Date:2011.
The Physical Object
- Description:1 online resource (129 pages)
Edition Identifiers
- ISBN:9781441996473, 1441996478
- DOI:10.1007/978-1-4419-9647-3
- oclc:ocn751682700
- LC Classification:QD505
- Dewey Decimal:541.395
Table of Contents
Kinetic and Thermodynamic Approaches for the Efficient Formation of Mechanical Bonds -- Efficient Templated Synthesis of Donor -- Acceptor Rotaxanes using Click Chemistry -- A One-Pot Synthesis of Constitutionally UnsymmetricalRotaxanes Using Sequential Cu(I)-Catalyzed Azide -- Alkyne Cycloadditions -- Heterogeneous Catalysis through Microcontact Printing -- Heterogeneous Catalysis of a Copper-Coated Atomic Force Microscopy Tip for Direct-Write Click Chemistry -- A Push-Button Molecular Switch -- Highly Stable TTF Radical Dimers in a Five-State [3]Catenane.
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