Polyoxometalate chemistry

by Cronin, Leroy Eldik, Rudi van

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Title Statements

Full title :Polyoxometalate chemistry / edited by Rudi van Eldik and Leroy Cronin.

Edition Statements

Publication Date:2017.

Publication Statements

Publisher(s):Academic Press
Place of Publication:Cambridge, MA
Language:eng
Publication Date:2017.

Notes

Includes index.

The Physical Object

Description:1 online resource

Edition Identifiers

oclc:ocn973493151
LC Classification:QD474
Dewey Decimal:541/.2242

Front Cover; Polyoxometalate Chemistry; Copyright; Contents; Contributors; Preface; Chapter One: Exploring Self-Assembly and the Self-Organization of Nanoscale Inorganic Polyoxometalate Clusters; 1. Introduction to Polyoxometalate Chemistry; 1.1. Background; 1.2. Classification of the Polyoxometalate Family; 2. From Serendipity to Directed Assembly; 3. Synthetic Methodologies; 3.1. Ligands and Metal Cations as Assembly Directing Motifs; 3.2. Templated Assembly; 3.3. Reductively Triggered Assembly; 4. POM-Based Supramolecular Structures; 4.1. POM Nanostructures

5. From Self-Assembled to Self-Organizing Cluster Systems6. Conclusions; References; Chapter Two: Supramolecular Structures Formation of Polyoxometalates in Solution Driven by Counterion-Macroion Interaction; 1. Introduction; 2. Self-Assembly of POM Macroions Into ``Blackberries;́́ 3. Counterion-Mediated Self-Assembly of POM Macroions; 3.1. Driving Force for Blackberry Formation; 3.2. Counterion Distribution in POM Solutions; 3.3. Counterion Exchange Around POMs; 3.4. Self-Assembly With Anisotropic Surface Charge Density Distribution; 4. The Kinetic Properties and Lag Phase of POM Assembly

5. POM-Counterion Ion Pairing in So…