Transition-metal-mediated aromatic ring construction

"Recent significant advances with transition-metal-mediated reactions have opened promising new routes to complex aromatic compounds and have been the subject of intense research in recent years. Featuring practical and efficient reactions to help organic chemists synthesize an important class of compounds, Transition-Metal-Mediated Aromatic Ring Construction provides a valuable guide to methods, synthetic routes, and strategies to construct aromatic rings. Chapters devoted to efficient and practical reactions demonstrate how to use them for the synthesis of various complex aromatic compounds"--

"This book covers transition-metal-mediated reactions with applications for constructing aromatic rings, which are an important class of industrial chemical compounds"--

Title Page; Copyright; Contributors; Preface; Part I: [2 + 2 + 2] and Related Cycloaddition Reactions; Chapter 1: Cobalt-Mediated [2 + 2 + 2] Cycloaddition; 1.1 INTRODUCTION; 1.2 SYNTHESIS OF BENZENES; 1.3 SYNTHESIS OF HETEROCYCLES; 1.4 MECHANISTIC ASPECTS; 1.5 SYNTHETIC APPLICATIONS; 1.6 SUMMARY AND OUTLOOK; REFERENCES; Chapter 2: Nickel-Mediated [2 + 2 + 2] Cycloaddition; 2.1 INTRODUCTION; 2.2 SYNTHESIS OF BENZENES; 2.3 CYCLOADDITION OF ALKYNES AND NITRILES; 2.4 CYCLOADDITION OF ALKYNES AND IMINES; 2.5 CYCLOADDITION OF ALKYNES AND CARBON DIOXIDE; 2.6 CYCLOADDITION OF ALKYNES AND ISOCYANATES.

2.7 CYCLOADDITION OF ALKYNES AND CARBODIIMIDE2.8 CYCLOADDITION OF DIYNES AND KETENES; 2.9 CYCLOADDITION OF ARYNES; 2.10 MECHANISM; 2.11 SUMMARY AND OUTLOOK; REFERENCES; Chapter 3: Ruthenium-Mediated [2 + 2 + 2] Cycloaddition; 3.1 INTRODUCTION; 3.2 SYNTHESIS OF BENZENES; 3.3 SYNTHESIS OF HETEROCYCLES; 3.4 MECHANISM OF RUTHENIUM-CATALYZED [2 + 2 + 2] CYCLOADDITIONS; 3.5 SYNTHETIC APPLICATIONS; 3.6 SUMMARY AND OUTLOOK; REFERENCES; Chapter 4: Rhodium-Mediated [2 + 2 + 2] Cycloaddition; 4.1 INTRODUCTION; 4.2 SYNTHESIS OF BENZENES; 4.3 SYNTHESIS OF PYRIDINES.

4.4 SYNTHESIS OF PYRIDONES AND RELAT…