In this work new Raman spectroscopic experiments on rare earth metal-rare earth trihalide melts (Ln-LnX3 and LnX2-LnX3: Ln=Ce, Nd; X=Cl, I) and their mixtures in alkali halide eutectic solvents ((LiX-KX)eu; X=Cl, I) are presented. The main results can be summarized as follows:- …