Prior studies of groundwater systems have associated increasing salinity and anoxic conditions with increasing radium (Ra) activities in water due to the decreasing effectiveness of Ra removal processes. However, the components of salinity (e.g. Ca vs. Na and SO42- vs. Cl-domina…
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An investigation into the processes taking place at the surface interface of ferroelectric Pb(Zr1-x,Tix)O3 immersed in metal salt solution under ultraviolet illumination is presented. The semiconducting and switchable dipolar nature of this material allows the spatial separation…
This dissertation establishes a comprehensive approach to looking at aqueous equilibria phenomena over essentially all feasible compositions of two component solutions - acid-base titrations, metal-ligand complexation, oxidation-reduction couples and solubility of binary ionic c…
The main objectives of this research program will be (1) the rational design of bifunctional supported metal oxide catalyst containing redox and acid sites (2) developing next generation bifunctional supported metal oxides catalysts for enhanced performance by molecularly tuning…
The redox conditions of Earth have been changing since proto-Earth’s accretion from the solar nebula. These changes have influenced the distribution and partitioning of volatile elements between the atmosphere and the mantle (Righter et al., 2020; Stagno and Fei, 2020. Though ox…
Isotope ratios of some trace metals have proven useful for tracking Earth’s ocean oxygenation history. As the limitations of some of these isotope systems are realized, it becomes increasingly important to develop new and complementary systems. This dissertation examines the uti…
The chemistry of actinides in solution is a very important aspect of the nuclear fuel cycle, especially as the energy needs of the world continue to increase. However, the radio-active nature of the actinides makes experimentation very difficult and dedicated expensive instrumen…