A general synthetic approach to diterpenoids of the cis-clerodane family has been developed, culminating in the first total synthesis, in racemic form, of ({\pm})-6β-acetoxy-2-oxokolavenool (85) and ({\pm})-2-oxo-5α ,8α-13,14,15,16-tetranorclerod-3-en-12-oic acid (86). The key o…
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