Despite significant structural differences between the active sites of supported vanadium oxide catalysts such as supported VO4/SiO 2, and vanadium bromoperoxidase enzyme mimics such as the vanadium peroxo-oxo compound chelated with N-(2-hydroxyethyl)iminodiacetic acid (heida) o…
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Magnetic resonance study was carried out for four vanadium model compounds containing sulfur and nitrogen heteroatoms at 9GHz. These systems are Bis(S-methyl-3-isopropyllidenehydrazinecarbodithioto)oxovana- dium(IV); (V1); and Bis(S-methyl-3-cyclohexylidenehydrazinecarbodi- thio…
An exploration of some early transition metal (oxy) fluoride systems using solvothermal techniques has been carried out. 30 novel materials have been synthesised, which fall into three classes based on different metal centres; vanadium (21), molybdenum (5) and niobium (4). Some …